CORROSION BEHAVIOR OF LOW ALLOY Ni-Cr-Mo STEEL AFTER HOT FORGING FOLLOWED BY INTERCRITICAL HEATING FOR WEATHERED RESISTANT FASTENER
DOI:
https://doi.org/10.21776/jrm.v13i2.1055Keywords:
Cyclic Polarization, Hot Forging, Intercritical Heating, Low Ni-Cr-Mo alloyAbstract
Low Ni-Cr-Mo alloys is developed by thermomechanical process to obtain high strength, toughness, and great hardenability properties. the aim of this study is to determine the correlation between the microstructure and corrosion properties after hot forging and followed by intercritical heating with cooling rate variation. Low Ni-Cr-Mo steel was homogenized, hot forgings at 950℃, and heat treated at 880℃ with three cooling variations by water, oil, and air. Intercritical heating makes a dual-phase structure. Metallorgaphy and hardness test is confirmed a mechanical properties. OCP and cyclic polarization test is confirmed a corrosion behavior. As the fast-cooling (water quenchant) show the lath martensite, bainite, and a few of acicular ferrite. The hardness of the 75-ton result is slightly lower than the 50-ton load, is reached 591±9.4 VHN for 75-ton and 597±15.6 VHN for 50-ton. Polarization test resulted corrosion resistance sample with 100 ton forging water quench has a high corrosion rate 0.8 mpy, higher than air quench 0.01 mpy.
References
ARULMANI, L., SHRIDHARMURTHY, H. N., SELVAN, M.C.P., and MADARA, S.R., “Hot powder forging behavior analysis of sintered AISI 8740 PM steels for automotive application,” Mater. Today Proc., v. 28, n. 2, February, pp. 1068–1072, 2019, doi: 10.1016/j.matpr.2020.01.079.
ALVES, H., and HEUBNER, U., Aqueous Corrosion of Nickel and its Alloys, 1st ed., Amsterdam: Elsevier Ltd., 2016.
HOU, Y., LI, Y., ONODERA, E., ZHANG, C., KOIZUMI, Y., and CHIBA, A., “Ex-situ observation on the dissolution behaviour of Ni-16Cr-15Mo and Ni-30Co-16Cr-15Mo alloys in hydrofluoric acid,” Corros. Sci., v. 90, pp. 133–139, 2015, doi: 10.1016/j.corsci.2014.10.003.
YANG, B., LI, J., GONG, X., NIE, Y., and LI, Y., “Effects of Cu addition on the corrosion behavior of NiCoCrMo alloys in neutral chloride solution,” RSC Adv., v. 7, n. 65, pp. 40779–40790, 2017, doi: 10.1039/c7ra05617f.
SUGIMOTO, K.I., SATO, S. H., KOBAYASHI, J., and SRIVASTAVA, A.K., “Effects of Cr and Mo on mechanical properties of hot-forged medium carbon TRIP-aided bainitic ferrite steels,” Metals (Basel)., v. 9, n. 10, p. 1066, 2019, doi: 10.3390/met9101066.
ANGELESCU, M.L., COJOCARU, V.D., ŞERBAN, N., and COJOCARU, E.M., “Evaluation of optimal forging temperature range for an industrial UNS S32750 SDSS alloy using SEM-EBSD analysis,” Metals (Basel)., v. 8, n. 7, 2018, doi: 10.3390/met8070496.
M. F. ASHBY AND D. R. H. JONES, “Steels 2—Alloy Steels,” In: Eng. Mater. 2, pp. 221–236, 2013, doi: 10.1016/b978-0-08-096668-7.00013-9.
HERBIROWO, S., SYAHRUM, M., HASBI, M.Y., CHANDRA, S.A., RIDLO, F.M., and ADJIANTORO, B., “Mechanical and microstructure properties of the Ni-Cr-Mo modified steel by heat treatment process,” IOP Conf. Ser. Mater. Sci. Eng., vol. 541, no. 1, p. 012014, 2019, doi: 10.1088/1757-899X/541/1/012014.
NAKHAIE, D., and MOAYED, M.H., “Pitting corrosion of cold rolled solution treated 17-4 PH stainless steel,” Corros. Sci., v. 80, pp. 290–298, 2014, doi: 10.1016/j.corsci.2013.11.039.
HONG, S., et al., “Effect of cooling rate on mechanical properties of SA508 Gr.1A steels for main steam line piping in nuclear power plants,” Int. J. Press. Vessel. Pip., v. 191, February, p. 104359, 2021, doi: 10.1016/j.ijpvp.2021.104359.
TARTAGLIA, J.M., KUELZ, A.N. and THELANDER, V.H., “The Effects of Alloying Elements on the Continuous Cooling Transformation Behavior of 2¼Cr-1Mo Steels,” J. Mater. Eng. Perform., v. 27, no. 12, pp. 6349–6364, 2018, doi: 10.1007/s11665-018-3683-1.
ZHOU, X., CHEN, Y., JIANG, Y., and LI, Y., “Effects of plastic deformation on austenite transformation in Fe-1.93Mn-0.07Ni-1.96Cr-0.35Mo ultra-high strength steel during continuous cooling,” Mater. Res. Express, v. 6, no. 12, pp. 0–9, 2019, doi: 10.1088/2053-1591/ab6e7c.
GARZA, E.I.S., “Mechanical Properties and Microstructure of Large Steel Forgings for Applications in the Energy Sector,”, Thesis, The University of Sheffield, 2017.
YANG, X., et al., “Effect of Cooling Rate and Austenite Deformation on Hardness and Microstructure of 960MPa High Strength Steel,” Sci. Eng. Compos. Mater., v. 27, pp. 415–423, 2020, doi: 10.1515/secm-2020-0045.
TASH, M.M., ALKAHTANI, S.A., and ABUHASEL, K.A., “Effect of Hot Work on Hardness and Impact Toughness of Heat Treated Low Alloy Steels,” Adv. Mater. Res., v. 1082, February 2016, pp. 197–201, 2014, doi: 10.4028/www.scientific.net/amr.1082.197.
BUDIANTO, E., CHOIRON, M.A., and DARMADI, D.B., “Hardening Baja AISI 1045 Menggunakan Gel Aloe Vera Sebagai Media Pendingin,” J. Rekayasa Mesin, v. 7, n. 2, pp. 55–64, 2016, doi: 10.21776/ub.jrm.2016.007.02.3.
CHU, Y., CHEN, Y., CHEN, Y., LIU, P., and LI, X., “Microstructure and Corrosion Behavior of Ni-Cr-Mo Nickel-based Alloy Weld,” Mater. Res., v. 23, n. 6, pp. 1–9, 2020, doi: 10.1590/1980-5373-MR-2019-0631.
ANGGRIAWAN, O., CHOIRON, M.A., and LIN, J., “Pengaruh Waktu Pemanasan (Anil) Terhadap Ketahanan Korosi Pada Gelas Metalik Berbasis Zirkonium,” Rekayasa Mesin, v. 5, n. 3, pp. 193–199, 2014.
LI, X., and OGLE, K., “The Passivation of Ni-Cr-Mo Alloys: Time Resolved Enrichment and Dissolution of Cr and Mo during Passive-Active Cycles,” J. Electrochem. Soc., v. 166, n. 11, pp. C3179–C3185, 2019, doi: 10.1149/2.0201911jes.
ANSARI, T.Q., LUO, J.L., and SHI, S.Q., “Modeling the effect of insoluble corrosion products on pitting corrosion kinetics of metals,” npj Mater. Degrad., v. 3, pp. 1–12, 2019, doi: 10.1038/s41529-019-0090-5.
SHERIF, E.S.M., “A comparative study on the electrochemical corrosion behavior of iron and X-65 steel in 4.0 wt % sodium chloride solution after different exposure intervals,” Molecules, v. 19, n. 7, pp. 9962–9974, 2014, doi: 10.3390/molecules19079962.
QIAN, Y.H., NIU, D., XU, J.J. and LI, M.S., “The influence of chromium content on the electrochemical behavior of weathering steels,” Corros. Sci., v. 71, pp. 72–77, 2013, doi: 10.1016/j.corsci.2013.03.002.
ESMAILZADEH, S., ALIOFKHAZRAEI, M., and SARLAK, H., “Interpretation of Cyclic Potentiodynamic Polarization Test Results for Study of Corrosion Behavior of Metals: A Review,” Prot. Met. Phys. Chem. Surfaces, vol. 54, pp. 976–989, 2018, doi: 10.1134/S207020511805026X.
BÖSING, I., BOBROV, I., EPP, J., BAUNE, M., and THÖMING, J., “Influence of systematically changed martensite content on the passive film properties of austenitic stainless steel in neutral electrolyte,” Int. J. Electrochem. Sci., v. 15, pp. 319–333, 2020, doi: 10.20964/2020.01.09.
WEI, J., DONG, J. H., KE, W., and HE, X.Y., “Influence of inclusions on early corrosion development of ultra-low carbon bainitic steel in NaCl solution,” Corrosion, v. 71, n. 12, pp. 1467–1480, 2015, doi: 10.5006/1837.
NEETU, KATIYAR, P.K., SANGAL, S., and MONDAL, K., “Effect of various phase fraction of bainite, intercritical ferrite, retained austenite and pearlite on the corrosion behavior of multiphase steels,” Corros. Sci., vol. 178, p. 109043, 2021, doi: 10.1016/j.corsci.2020.109043.
SHI, Y., et al., “Homogenization of AlxCoCrFeNi high-entropy alloys with improved corrosion resistance,” Corros. Sci., vol. 133, pp. 120–131, 2018, doi: 10.1016/j.corsci.2018.01.030.
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